top of page
Rechercher

FIRST USE OF AN ORGANOBISMUTH REAGENT IN C(SP3)–S BOND FORMATION

  • Photo du rédacteur: Groupe Gagnon
    Groupe Gagnon
  • 15 août 2019
  • 1 min de lecture

Dernière mise à jour : 5 juil. 2020

First use of an organobismuth reagent in C(sp3)–S bond formation: Access to aryl cyclopropyl sulfides via copper-catalyzed S-cyclopropylation of thiophenols using tricyclopropylbismuth





The direct S-cyclopropylation of thiophenols using tricyclopropylbismuth is reported. The reaction is catalyzed by copper(II) acetate and operates under mild conditions to afford the corresponding aryl cyclopropyl sulfides in moderate to good yields. This reaction represents the first use of an organobismuth reagent in C(sp3)–S bond formation.


Emeline Benoit, Bianca Bueno and Alexandre Gagnon





 
 
 

Comentarios


Logouqam quadrille.png

Alexandre Gagnon, Ph.D.

Professeur titulaire

Université du Québec à Montréal, Département de chimie

2101 Rue Jeanne-Mance, Montréal, Québec, Canada, H2X 2J6

Email: gagnon.alexandre@uqam.ca

Tel: 514.987.3000 ext 6856

  • LinkedIn Social Icône

Designed and created by Bianca Bueno and Alexandre Gagnon

© 2020 Alexandre Gagnon

bottom of page